Vapor−Liquid Equilibria for Acetone + Chloroform + Methanol and Constituent Binary Systems at 101.3 kPa

Molecular modeling of phase behavior and microstructure of acetone-chloroform-methanol binary mixtures.

Force fields based on a Lennard-Jones (LJ) 12-6 plus point charge functional form are developed for acetone and chloroform specifically to reproduce the minimum pressure azeotropy found experimentally in this system. Point charges are determined from a CHELPG population analysis performed on an acetone-chloroform dimer. The required electrostatic surface for this dimer is determined from ab ini...

Vapor-liquid equilibria for methanol + fatty acid methyl ester binary systems near critical temperature of methanol

In biodiesel production processes using supercritical methanol, the phase equilibria for methanol + fatty acid methyl ester systems near the critical temperature of methanol (Tc = 512.6 K) are required as the fundamental data. A flow type method was applied to measure the vapor-liquid equilibria for methanol + fatty acid methyl ester binary systems at 493 – 543 K. The phase behavior was studied...

Free Radical-scavenging and Antimutagenic Potential of Acetone, Chloroform and Methanol Extracts of Leaf of Argemone Mexicana

Antioxidant and antimutagenic potency of acetone, chloroform and methanol extracts of Argemone mexicana leaves were investigated by employing nitroblue tetrazolium and Ames assay. Maximum superoxide anion radicals scavenging responses noticed were 84.0, 81.0 and 75.0 % in acetone, methanol and chloroform extracts at a dose of 200μg/ml. Inhibitory potential was compared with the standard (L-asco...

Prediction of Liquid-Liquid Equilibria of Binary Systems Containing Alcohols Using EoS-GE Models

Mutual diffusion of binary liquid mixtures containing methanol, ethanol, acetone, benzene, cyclohexane, toluene, and carbon tetrachloride.

Mutual diffusion coefficients of all 20 binary liquid mixtures that can be formed out of methanol, ethanol, acetone, benzene, cyclohexane, toluene, and carbon tetrachloride without a miscibility gap are studied at ambient conditions of temperature and pressure in the entire composition range. The considered mixtures show a varying mixing behavior from almost ideal to strongly non-ideal. Predict...